Influence of in-office whitening gel pH on hydrogen peroxide diffusion through enamel and color changes in bovine teeth

Purpose: To assess the influence of in-office whitening gel pH on whitening efficiency. Methods: Hydrogen peroxide diffusion and color changes on bovine teeth were assessed. Three gels with close hydrogen peroxide concentrations but with various pH levels were tested: Zoom 2 (Discus Dental), Opalescence Endo and Opalescence Boost (Ultradent). The pH levels were respectively: 3.0, 5.0 and 7.0. Thirty enamel slices and tooth crowns were used for both studies (n=10 per group per study). Hydrogen peroxide diffusion through the enamel slices and the tooth crowns was spectrophotometrically recorded every 10 minutes for 1 hour to calculate the diffusion coefficients. Color changes were spectrophotometrically recorded every 10 minutes for 1 hour and quantified in term of CIE-Lab. Results: The hydrogen peroxide diffusion coefficient through enamel ranged from 5.12 +/- 0.82 x 10(-9) cm(2) s(-1) for pH 3 to 5.19 +/- 0.92 x 10(-9) cm(2) for pH 7. Through tooth crowns it ranged from 4.80 +/- 1.75 x 10(-10) cm(2) s(-1) for pH 5 to 4.85 +/- 1.82 x 10(-10) cm(2) s(-1) for pH 3. After I hour, the Delta E varied from 5.6 +/- 4.0 for pH 7 to 7.0 +/- 5.0 for pH 3 on enamel slices and from 3.9 +/- 2.5 for pH 5 to 4.9 +/- 3.5 for pH 7 on tooth crowns. There was no statistically significant difference between groups for both parameters. (Am J Dent 2012:25:91-96).