Palladium-catalyzed intermolecular C-H amidation of indoles with sulfonyl azides

被引：11
|
作者：
Hu, Ziwei [1 ,2 ]
Luo, Shuang [1 ,2 ]
Zhu, Qiang [1 ,2 ]
机构：
[1] Chinese Acad Sci, State Key Lab Resp Dis, Guangzhou 510530, Guangdong, Peoples R China
[2] Chinese Acad Sci, Guangzhou Inst Biomed & Hlth, Guangzhou 510530, Guangdong, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2015年 / 58卷 / 08期
基金：
中国国家自然科学基金;
关键词：
C-H amidation; indole; palladium; sulfonyl azide; CARBON-NITROGEN BONDS; DIRECT AMINATION; ARENES; CHLOROAMINES; C(SP(2))-H; ACTIVATION; ISOCYANIDE; AZOLES;
D O I：
10.1007/s11426-015-5369-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new kind of intermolecular indole C-H amidation reaction catalyzed by the most frequently used palladium catalyst has been developed. Sulfonyl azide was employed as an innovative nitrogen source and environmentally benign nitrogen was produced as the only byproduct.
引用
收藏
页码：1349 / 1353
页数：5
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