Nanoscale lattice fluctuations in cuprates and manganites

被引:26
|
作者
Bianconi, A [1 ]
Saini, NL [1 ]
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
来源
关键词
lattice distortions; nanoscale heterogeneitics; cuprates; manganites;
D O I
10.1007/b101023
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Local lattice displacements giving a nanoscale inhomogeneous pattern due to mesoscopic phase separation in the correlated transition metal perovskites play a distinct role for high T, superconductivity (HTcS) in the copper oxides and for colossal magneto resistance (CMR) in manganese oxides. Experimentally the local structure physics of these correlated oxides owes a lot to the extended X-ray absorption fine structure (EXAFS) using polarized synchrotron radiation sources, a local and fast experimental probe that has revealed several key structural aspects. Here we have briefly reviewed some of our studies on the local displacements in the electronically active Cu-O lattice in the copper oxide superconductors and the Mn-O lattice of the manganese oxide CMR and charge ordered systems, exploiting the EXAFS technique. In the copper oxides the determination of polaronic distortions by polarized Cu-K-edge EXAFS has revealed superlattice of distorted stripes intercalated with undistorted stripes with the chemical potential tuned near a shape resonance for the interband scattering in a system with two electronic components that can amplify the critical temperature. On the other hand, the Mn K-edge EXAFS has been applied to underline the importance of the local Mn-O displacements to characterize various phases in the perovskite manganese oxides.
引用
收藏
页码:287 / 330
页数:44
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