Heterogeneously catalysed Strecker-type reactions using supported Co(II) catalysts: microwave vs. conventional heating

被引：39

作者：

Rajabi, Fatemeh ^{[1
]}

Nourian, Saghar ^{[2
]}

Ghiassian, Sara ^{[2
]}

Balu, Alina M. ^{[3
]}

Saidi, Mohammad Reza ^{[2
]}

Carlos Serrano-Ruiz, Juan ^{[3
]}

Luque, Rafael ^{[3
]}

机构：

[1] Payame Noor Univ, Dept Sci, Tehran, Iran

[2] Sharif Univ Technol, Dept Chem, Tehran, Iran

[3] Univ Cordoba, Dept Quim Organ, E-14014 Cordoba, Spain

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 11期

关键词：

ALPHA-AMINO-ACIDS; SOLVENT-FREE SYNTHESIS; ASYMMETRIC-SYNTHESIS; EFFICIENT CATALYST; AEROBIC OXIDATION; HIGHLY EFFICIENT; COBALT COMPLEX; AMINONITRILES; SILICA; KETIMINES;

D O I：

10.1039/c1gc15741h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A range of alpha-aminonitriles could be efficiently prepared from various aldehydes/ketones and primary or secondary amines using a highly active and stable Co(II) complex supported on different mesoporous supports at both room temperature and low temperature microwave irradiation under solventless conditions. Catalysts were also highly reusable under the investigated reaction conditions and could be reused at least 10 times without loss of catalytic activity.

引用

页码：3282 / 3289

页数：8

共 10 条

[1] Efficient Co(II) heterogeneously catalysed synthesis of α-aminonitriles at room temperature via Strecker-type reactions
Rajabi, Fatemeh
Ghiassian, Sara
Saidi, Mohammad Reza
GREEN CHEMISTRY, 2010, 12 (08) : 1349 - 1352
[2] A versatile supported cobalt(II) complex for heterogeneously catalysed processes: conventional vs. microwave irradiation protocols
Rajabi, Fatemeh
Balu, Alina M.
Toreinia, Fatemeh
Luque, Rafael
CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (06) : 1051 - 1059
[3] Intensification of oxidation and epoxidation reactions-Microwave vs. conventional heating
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Bednarz, Szczepan
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Kasprzyk, Wiktor
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2018, 132 : 208 - 217
[4] Kinetics of palladium-catalyzed reactions heated by microwave vs. conventional heating
Yeboah, Kwadwo
Jackson, Daniel
Shepherd, Cameron
Kyeremateng, Kizito
Potts, Alan
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ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
[5] Organosoluble copper clusters as catalysts for carbon-oxygen bond forming reactions: Microwave vs. conventional heating.
Stockland, RA
Manbeck, J
Lipman, AJ
Freidl, A
Hasler, A
Guzei, IA
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U882 - U883
[6] Friedel-Crafts acylation reactions using heterogeneous catalysts stimulated by conventional and microwave heating
Bond, G.
Gardner, J. A.
McCabe, R. W.
Shorrock, D. J.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 278 (1-2) : 1 - 5
[7] Nickel(II) catalysed co-polymerisation of CO and ethene: Formation of polyketone vs. polyethylene - The role of co-catalysts
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[8] Evaluation of acid catalysts and conventional vs. microwave heating in the acid-catalyzed synthesis of biodiesel from vegetable oil
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O'Brien, Michael R.
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Rhoads, Kevin P.
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ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
[9] Selective epoxidation of alkenes using highly active V-SBA-15 materials: microwave vs. conventional heating
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JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (45) : 8603 - 8609
[10] WGS and CO-PrOx reactions using gold promoted copper-ceria catalysts: "Bulk CuO-CeO2 vs. CuO-CeO2/Al2O3 with low mixed oxide content"
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APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 197 : 62 - 72

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