Coordination Compounds of Cobalt(II), Nickel(II), and Copper(II) Halides with 2-Methyl-1,2,4-Triazolo[1,5-a]benzimidazole

被引：7
|
作者：
Dyukova, I. I. [1 ,2 ]
Kuz'menko, T. A. [3 ]
Komarov, V. Yu. [1 ,2 ]
Sukhikh, T. S. [1 ,2 ]
Vorontsova, E. V. [4 ]
Lavrenova, L. G. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Novosibirsk Natl State Res Univ, Novosibirsk 630090, Russia
[3] Southern Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu, Russia
[4] Fed Res Ctr Fundamental & Translat Med, Inst Mol Biol & Biophys, Novosibirsk, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 44卷 / 12期
基金：
俄罗斯基础研究基金会;
关键词：
synthesis; complexes; 3d metals; 2-methyl-1; 2; 4-triazolo[1; 5-a]benzimidazole; X-ray structure analysis; electronic spectroscopy; IR spectroscopy; cytotoxic activity; ANTIMICROBIAL ACTIVITY; COMPLEXES; BENZIMIDAZOLE; 1,2,4-TRIAZOLE; ANTIBACTERIAL; THIABENDAZOLE; PLATINUM(II); IMIDAZOLE; CU(II); CO(II);
D O I：
10.1134/S107032841812014X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New coordination compounds of Co(II), Ni(II), and Cu(II) halides with 2-methyl-1,2,4-triazolo[1,5-a]benzimidazole (L), [Co(L)(2)Cl-2] (Ia), [Ni(L)(2)(H2O)(4)]Cl-2 4H(2)O (II), and [Cu-2(L)(4)(mu-Br)(2)Br-2] (IIIa), are synthesized. The complexes are studied by X-ray structure analysis (CIF files CCDC nos. 1825006-1825008), electronic (diffuse reflectance) spectroscopy, and IR spectroscopy. In compounds Ia, II, and IIIa, ligand L is coordinated to the metal by the N-4 atom of the triazole fragment. The study of the cytotoxic effect of the ligand and synthesized complexes on the Hep-2 line (laryngeal cancer cells) shows a considerably higher activity of the copper(II) complex than that of the ligand.
引用
收藏
页码：755 / 764
页数：10
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