(2,2′-Biquinoline-κ2N,N′)bis(nitrato-κ2O,O′)copper(II)

被引：3

作者：

Moreno, Yanko

Salgado, Yimmy

Garland, Maria Teresa

Baggio, Ricardo

机构：

[1] Univ Concepcion, Fac Ciencias Quim, Dept Quim Anal & Inorgan, Concepcion, Chile

[2] Univ Chile, Dept Fis, Fac Ciencias Fis & Matemat, Santiago, Chile

[3] Univ Chile, CIMAT, Santiago, Chile

[4] Comis Nacl Energia Atom, Dept Fis, RA-1429 Buenos Aires, DF, Argentina

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S0108270107046513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title monomer, [Cu(NO3)(2)(C18H12N2)], the six-coordinated Cu-II atom lies on a twofold axis which bisects one of the ligands (a chelating biquinoline) and duplicates the remaining ligand, a chelating nitrate. The latter binds in a very asymmetric way, consistent with a Jahn-Teller distortion in the coordination polyhedron which, due to the triple chelation, is extremely distorted and difficult to describe in terms of any regular model.

引用

页码：M487 / M489

页数：3

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[1] (2,2′-biquinoline-κ2 N,N′)bis-(nitrato- κ2 O,O′)copper(II)
Departamento de Química Analítica e Inorgánica, Facultad de Ciencias Químicas, Universidad de Concepción, Casilla 233, Concepción, Chile
不详
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Acta Crystallogr Sect C Cryst Struct Commun, 1600, 11 (m487-m489):
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