C-S Bond Cleavage during Reactions between N,N-Diethylthiocarbamoyliminothianes and [MOCl4]- Complexes (M = Re, Tc)

被引：3

作者：

Hauenstein, Dirk ^{[1
]}

Hagenbach, Adelheid ^{[1
]}

Abram, Ulrich ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 12期

关键词：

Rhenium; Technetium; Tridentate benzamidines; Oxo complexes; Structure analysis; RAY CRYSTAL-STRUCTURE; MIXED-LIGAND COMPLEXES; RHENIUM; TECHNETIUM;

D O I：

10.1002/zaac.201100359

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[MOCl4](-) complexes (M = Re, Tc) react with thianes derived from N-[(diethylamino)(thiocarbonyl)]benzamidoyl chloride and 2-mercaptophenol (HL1) and 2-mercaptoaniline (HL2) under C-S bond cleavage and formation of oxorhenium(V) and oxotechnetium(V) complexes with the resulting decomposition products 2-mercaptophenol and N-[(dialkylamino)thiocarbonyl]-N'-2-mercaptophenyl)benzamidine (H2L2a), respectively. The products, (NBu4)[ReO(S,O-C6H4)(2)], [ReOCl(L-2a)] and [TcO(L-2a)] were obtained in good yields and isolated in crystalline form. Single-crystal X-ray studies reveal square-pyramidal coordination environments with apical oxo ligands for all three product complexes under study.

引用

页码：1889 / 1894

页数：6

共 50 条

[1] C-N, C-S and S-S Bond Cleavage by Rhodium PCcarbeneP Pincer Complexes
Tinnermann, Hendrik
Young, Rowan D.
CHEMISTRY-AN ASIAN JOURNAL, 2020, 15 (18) : 2873 - 2878
[2] Recent advances in cyclization reactions of isatins or thioisatins via C-N or C-S bond cleavage
Shen, Jinhui
Zhang, Lei
Meng, Xiangtai
ORGANIC CHEMISTRY FRONTIERS, 2021, 8 (22): : 6433 - 6451
[3] Studies of C-S bond cleavage reactions of Re(V) dithiolates: Synthesis, reactivity, and mechanism
Li, M
Ellern, A
Espenson, JH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (29) : 10436 - 10447
[4] CLEAVAGE OF C-S BOND DURING REDUCTION OF SULFONES BY LIALH4
DUFORT, N
JODOIN, B
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1978, 56 (13): : 1779 - 1781
[5] Dioxygen-triggered oxidative cleavage of the C-S bond towards C-N bond formation
Lv, Zongchao
Wang, Huamin
Quan, Zhicong
Gao, Yuan
Lei, Aiwen
CHEMICAL COMMUNICATIONS, 2019, 55 (82) : 12332 - 12335
[6] C-S Bond Cleavage, Redox Reactions, and Dioxygen Activation by Nonheme Dicobalt(II) Complexes
Jana, Manish
Majumdar, Amit
INORGANIC CHEMISTRY, 2018, 57 (02) : 617 - 632
[7] C-S bond cleavage by chloride in a thioether N2S2 complex of platinum
Hanton, LR
Lee, K
INORGANIC CHEMISTRY, 1999, 38 (07) : 1634 - +
[8] DszA Catalyzes C-S Bond Cleavage through N5-Hydroperoxyl Formation
Ferreira, Pedro
Neves, Rui P. P.
Miranda, Filipa P.
Cunha, Ana V.
Havenith, Remco W. A.
Ramos, Maria J.
Fernandes, Pedro A.
JOURNAL OF CHEMICAL INFORMATION AND MODELING, 2024, 64 (10) : 4218 - 4230
[9] Iron Porphyrin Complexes Catalyzed Cyclopropanation Reactions and C-S Bond Cleavage Reactions for Phenyl Vinyl Sulfides and Diazoreagents
Yan, Xiaojing
Li, Chang
Jin, Zhixiong
Xu, Xiaofei
Chen, Weiwei
Pan, Yuanjiang
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (11) : 3837 - 3846
[10] Theoretical studies of the reductive C-S bond cleavage in complexes of the form [M(9S3)2]2+ (M = Re, Tc, and Ru; 9S3=1,4,7-trithiacyclononane)
Maurer, P
Magistrato, A
Rothlisberger, U
JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (52): : 11494 - 11499

← 1 2 3 4 5 →