Supramolecular architecture of silver(I) coordination polymers containing polydentate N-donor ligands

被引：44

作者：

Chainok, Kittipong ^{[1
,2
]}

Neville, Suzanne M. ^{[1
]}

Forsyth, Craig M. ^{[1
]}

Gee, William J. ^{[1
]}

Murray, Keith S. ^{[1
]}

Batten, Stuart R. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Suranaree Univ Technol, Sch Chem, Inst Sci, Nakhon Ratchasima 30000, Thailand

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 10期

基金：

澳大利亚研究理事会;

关键词：

COMPLEXES; CRYSTAL; CONSTRUCTION; COPPER(II); CHEMISTRY; ELEMENTS; DESIGN;

D O I：

10.1039/c2ce25225b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the polydentate N-donor ligands bmtz, H(2)bmtz, and bptz with various silver salts was investigated. New 1D coordination polymers [Ag-2(bmtz) (ClO4)]ClO4 (1), [Ag(bmtz)]ClO4 center dot MeCN (2), [{Ag(tcm)}(2)(H(2)bmtz)(MeCN)] (3) and [Ag(bptz)(NO3)] (5), and 2-D sheet structures, [{Ag(tcm)}(2)bmtz] (4), were synthesized. The structures are built up through the combination of coordination bonds, hydrogen bonding, Ag-pi, pi-pi, and anion-pi interactions to generate new supramolecular architectures. The supramolecular structure of the protonated amine salt [H(2)bptz](NO3)(2) (6) is also described.

引用

页码：3717 / 3726

页数：10

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