Polytype formation in GaAs/GaP axial nanowire heterostructures

被引:21
|
作者
Boulanger, Jonathan P. [1 ]
LaPierre, Ray R. [1 ]
机构
[1] McMaster Univ, Dept Engn Phys, Ctr Emerging Device Technol, Hamilton, ON L8S 4L7, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Crystal structure; Nanostructures; Planar defects; Molecular beam epitaxy; Semiconducting III-V materials; Nanowire; CORE-SHELL NANOWIRES; BEAM EPITAXY; GROWTH; INAS; TRANSISTORS; NANOWHISKERS;
D O I
10.1016/j.jcrysgro.2011.07.021
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Transmission electron microscopy (TEM) studies are presented for Au-assisted vapor-liquid-solid (VLS) nanowire growth of gallium arsenide/gallium phosphide (GaAs/GaP) axial heterostructures. The supersaturation of the liquid Au-III-V alloy droplet during MBE growth was found to have a profound impact on both the crystal phase and growth rate of the nanowire heterostructures. Among these effects was the appearance of a previously unreported 4H GaP crystal phase. 4H GaP occurred at low Au-III-V droplet supersaturation following the transition from GaAs to GaP growth. Both crystal phase and growth rate were different for GaAs and GaP, underlining the importance of group V elements in Au-III-V droplet supersaturation and thus VLS nanowire growth. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:21 / 26
页数:6
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