Novel Efficient Procedure for the Conjugate Addition of Amines to Electron Deficient Alkenes

被引:2
|
作者
Sun, Xudong [1 ]
Du, Yijun [1 ]
Li, Chunqing [1 ]
Qi, Chenze [1 ]
机构
[1] Shaoxing Univ, Inst Appl Chem, Shaoxing, Peoples R China
关键词
ASYMMETRIC MICHAEL ADDITION; ORGANOCATALYSTS; MALONONITRILE; PYRROLIDINE;
D O I
10.1134/S0023158410050058
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The novel efficient procedure has been developed for the conjugate addition of amines to electron deficient alkenes using the novel SO3H functionalized ionic liquid as catalyst. The results showed that the novel catalyst owned high activities for the reactions with excellent yields within several minutes. Various amines and electron deficient alkenes were successfully transformed to the corresponding products in the catalytic system. Operational simplicity, without need of any solvent, low cost of the catalyst used, room temperature, high yields, reusability, excellent chemoselectivity and wide applicability are the key features of this methodology.
引用
收藏
页码:653 / 656
页数:4
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