Spherical microporous/mesoporous activated carbon from pulping black liquor

被引:19
|
作者
Zhang, Jian [1 ]
Yu, Lianxiang [1 ]
Wang, Zichen [1 ]
Tian, Yumei [1 ]
Qu, Yuning [1 ]
Wang, Yan [1 ]
Li, Jiajing [1 ]
Liu, Hequn [1 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
关键词
pulping black liquor; spherical lignin; spheroidal activated carbon; environment-friendly; CHEMICAL ACTIVATION; LIGNIN; ADSORPTION;
D O I
10.1002/jctb.2627
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
BACKGROUND: A simple and effective method with environmental and economic benefits has been developed to produce spherical lignin and spheroidal microporous/mesoporous activated carbon from pulping black liquor. RESULTS: Spherical lignin with regular size of about 100 nm was obtained at 90 degrees C after 8 h treatment at pH 2. Pyrolysis of spherical lignin was impregnated with H3PO4 producing spheroidal microporous/mesoporous activated carbon with high apparent Brunauer-Emmett-Teller (BET) surface area of 1972 m(2) g(-1) and high carbon content of 68.0 wt% at 700 degrees C with impregnation ratio of 1:7. CONCLUSION: The process was inexpensive, sustainable, environment-friendly and suitable for large-scale production. (C) 2011 Society of Chemical Industry
引用
收藏
页码:1177 / 1183
页数:7
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