An EPR investigation of conductive polyaniline-poly(methyl methacrylate-co-acrylic acid) blends

被引:6
|
作者
Wu, K. H. [1 ,2 ]
Lai, Y. S. [1 ,2 ]
Shih, C. C. [3 ]
Wang, G. P. [3 ]
Yang, C. C. [3 ]
机构
[1] Chung Cheng Inst Technol, Dept Appl Chem, NDU, Tao Yuan 33509, Taiwan
[2] Chung Cheng Inst Technol, Dept Mat Sci, NDU, Tao Yuan 33509, Taiwan
[3] Chung Shan Inst Sci & Technol, Chem Syst Res Div, Tao Yuan 32544, Taiwan
关键词
D O I
10.1002/pc.20472
中图分类号
TB33 [复合材料];
学科分类号
摘要
A conductive blend of polyaniline (PANI) with sodium form poly(methyl methacrylate-co-acrylic acid) copolymer (PMMAA) was prepared by in situ dispersion polymerization. The PANI-PMMAA blends were characterized with UV-vis, FTIR, and electron paramagnetic resonance (EPR) spectra. The effects of PANI and temperature on the electronic properties of the PANI-PMMAA blends were studied with EPR technique. The PANI and temperature affect the intermolecular interaction between PANI and PMMAA and then determines the EPR parameters (A/B ratio, g factor, T-2, Delta H-pp, N-s, and lineshape).
引用
收藏
页码:902 / 905
页数:4
相关论文
共 50 条
  • [1] Electrically conducting polyaniline-poly(acrylic acid) blends
    Hu, HL
    Cadenas, JL
    Saniger, JM
    Nair, PK
    [J]. POLYMER INTERNATIONAL, 1998, 45 (03) : 262 - 270
  • [2] EPR studies of blends of polyaniline with poly(methyl methacrylate-co-glycidyl methacrylate iminodiacetic acid)
    Liu, HK
    Shih, CC
    Wang, GP
    Wu, TR
    Wu, KH
    Chang, TC
    [J]. SYNTHETIC METALS, 2005, 151 (03) : 256 - 260
  • [3] Magnetically loaded poly(methyl methacrylate-co-acrylic acid) nano particles
    F. Sayar
    G. Güven
    E. Pişkin
    [J]. Colloid and Polymer Science, 2006, 284 : 979 - 979
  • [4] Aqueous solutions of random poly(methyl methacrylate-co-acrylic acid): effect of the acrylic acid content
    Gyurova, Anna Y.
    Halacheva, Sylvia
    Mileva, Elena
    [J]. RSC ADVANCES, 2017, 7 (22) : 13372 - 13382
  • [5] Conductive blends of polyaniline with plasticized poly(methyl methacrylate)
    Juvin, P
    Hasik, M
    Fraysse, J
    Planès, J
    Pron, A
    Kulszewicz-Bajer, I
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1999, 74 (03) : 471 - 479
  • [6] Magnetically loaded poly(methyl methacrylate-co-acrylic acid) nano-particles
    F. Sayar
    G. Güven
    E. Pişkin
    [J]. Colloid and Polymer Science, 2006, 284 : 965 - 978
  • [7] Specific interactions in binary and ternary blends of poly(vinyl chloride) with poly(methyl methacrylate-co-acrylic acid) and poly(butyl methacrylate-co-4-vinylpyridine).
    Bouzouia, F
    Iguerb, O
    Bouyahia, R
    Djadoun, S
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 175 - POLY
  • [8] Blends of poly(isobutyl methacrylate) with poly(styrene-co-acrylic acid) and of poly(isobutyl methacrylate-co-acrylic acid) with poly(styrene-N, N-dimethylaminoethyl methacrylate)
    Hamou, A.S.H.
    Diadoun, S.
    Karasz, F.E.
    [J]. Polymer Preprints, Division of Polymer Chemistry, American Chemical Society, 1993, 34 (02):
  • [9] Absorptive and expansive behaviors of poly(methyl methacrylate-co-acrylic acid) bone cement
    Chen, Lei
    Tang, Yufei
    Zhao, Kang
    Liu, Jiaxin
    Bai, Hao
    Wu, Zixiang
    [J]. COLLOIDS AND SURFACES B-BIOINTERFACES, 2020, 189
  • [10] Hydrophilic Surface Modification of Poly(methyl methacrylate)/Poly(methyl methacrylate-co-acrylic acid) Composite Film by Surface Activation
    Sun, Xin
    Hu, Keling
    Wang, Kai
    Su, Chengkun
    Wang, Rui
    Ma, Zhengfeng
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2024, 225 (01)