Synthesis and Properties of Acetylene-bridged N-Confused Porphyrin Dimers

被引:15
|
作者
Toganoh, Motoki [1 ]
Takayama, Takumi [1 ]
Ritesh, Nandy [2 ]
Kimizuka, Nobuo [1 ,2 ]
Furuta, Hiroyuki [1 ,2 ]
机构
[1] Kyushu Univ, Dept Chem & Biochem, Grad Sch Engn, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, Int Res Ctr Mol Syst, Nishi Ku, Fukuoka 8190395, Japan
关键词
ENDOCYCLIC EXTENSION; PI-SYSTEM; TETRAPHENYLPORPHYRINS; SERIES; ISOMER;
D O I
10.1246/cl.2011.1021
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Acetylene-bridged N-confused porphyrin (NCP) dimers were synthesized by Stille coupling reactions. Moderate electronic interaction between the NCP chromophores was observed in the inner-3H tautomers while strong interaction was observed in the inner-2H tautomers.
引用
收藏
页码:1021 / 1023
页数:3
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