Click Reactivity of Azide-Modified Polyvinyl Chloride as an Entry to Glycopolymer Scaffolds

被引：1
|
作者：
Ay, Emriye [1 ,2 ]
Yenil, Nilgun [1 ]
机构：
[1] Manisa Celal Bayar Univ, Sci & Arts Fac, Dept Chem, Muradiye Campus, TR-45140 Manisa, Turkey
[2] Manisa Celal Bayar Univ, Sch Tobacco Expertise, Dept Tobacco Technol Engn, TR-45200 Akhisar, Manisa, Turkey
来源：
CROATICA CHEMICA ACTA | 2022年 / 94卷 / 03期
关键词：
protected-sugar alkynes; PVC-N-3; click reactions; 1,2,3-triazole; POLY(VINYL CHLORIDE); CHEMISTRY; TRIAZOLE;
D O I：
10.5562/cca3883
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the synthesis of new carbohydrate/triazole polymers based on poly(viny chloride) (PVC). Azide incorporation into commercially available PVC was carried out using nucleophilic substitution and Cu-catalyzed reaction of the resulting PVC-N-3 using three alkynyl-containing acetonide-protected monosaccharides (based on D-glucose and D-galactose) provided a set of PVC-based polymers incorporating a triazolyl linkage with monosaccharide moieties present on the periphery. Modified polymers were characterized by using Fourier transform infrared (FT-IR), Nuclear Magnetic Resonance (H-1-NMR and C-13-NMR) spectroscopy, together with thermogravimetric and surface morphological analysis.
引用
收藏
页码：166 / 175
页数：10
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