New Diterpene Glycosides from Stevia rebaudiana Bertoni: Rebaudioside VIII and Rebaudioside IXd

被引：0

作者：

Ma, Gil ^{[1
]}

Bechman, Allison ^{[1
]}

Bunders, Cynthia ^{[1
]}

Devkota, Krishna P. ^{[2
]}

Charan, Romila D. ^{[2
]}

Ramirez, Catherine ^{[2
]}

Snyder, Tara M. ^{[2
]}

Priedemann, Christopher ^{[2
]}

Prakash, Indra ^{[1
]}

机构：

[1] Coca Cola Co, One Coca Cola Pl, Atlanta, GA 30313 USA

[2] AMRI Albany, Analyt Dev, Albany, NY 12212 USA

来源：

NATURAL PRODUCT COMMUNICATIONS | 2018年 / 13卷 / 10期

关键词：

Diterpene glycosides; Structure elucidation; Rebaudioside; NMR; Stevia rebaudiana Bertoni; 1 -> 6 Glycoside linkage;

D O I：

暂无

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

With our interest of new diterpene glycosides with better taste profile than Rebaudioside M, we isolated and characterized two steviol glycosides with three additional glucose attached at the C-13 of Rebaudioside M or Rebaudioside D from an extract of Stevia rebaudiana Bertoni. Here we report the complete structure elucidations of diterpene glycosides on the basis of NMR experiments (H-1, C-13, COSY, HSQC-DEPT, HMBC, ID TOCSY, NOESY) and mass spectral data. Steviol glycosides that possess eight or nine glucose units are rarely reported in literature and could have an impact on the natural sweetener catalog.

引用

页码：1243 / 1250

页数：8

共 50 条

[1] Purification of rebaudioside A from Stevia rebaudiana Bertoni
Burghoff, B.
Bergs, D.
Joehnck, M.
Martin, G.
Schembecker, G.
STEVIA: BREAK-THROUGH IN EUROPE, 2011, : 167 - 178
[2] Rebaudioside F, a diterpene glycoside from Stevia rebaudiana
Starratt, AN
Kirby, CW
Pocs, R
Brandle, JE
PHYTOCHEMISTRY, 2002, 59 (04) : 367 - 370
[3] SWEET DITERPENE-GLYCOSIDES OF LEAVES OF STEVIA-REBAUDIANA BERTONI - SYNTHESIS AND STRUCTURE-SWEETNESS RELATIONSHIP OF REBAUDIOSIDE-A, REBAUDIOSIDE-D, REBAUDIOSIDE-E AND THEIR RELATED GLYCOSIDES
KASAI, R
KANEDA, N
TANAKA, O
YAMASAKI, K
SAKAMOTO, I
MORIMOTO, K
OKADA, S
KITAHATA, S
FURUKAWA, H
NIPPON KAGAKU KAISHI, 1981, (05) : 726 - 735
[4] Improvement of rebaudioside A diterpene glycoside content in Stevia rebaudiana Bertoni using clone selection
Kaplan, Begum
Turgut, Kenan
TURKISH JOURNAL OF AGRICULTURE AND FORESTRY, 2019, 43 (02) : 232 - 240
[5] Isolation and Characterization of a Novel Rebaudioside M Isomer from a Bioconversion Reaction of Rebaudioside A and NMR Comparison Studies of Rebaudioside M Isolated from Stevia rebaudiana Bertoni and Stevia rebaudiana Morita
Prakash, Indra
Bunders, Cynthia
Devkota, Krishna P.
Charan, Romila D.
Ramirez, Catherine
Priedemann, Christopher
Markosyan, Avetik
BIOMOLECULES, 2014, 4 (02) : 374 - 389
[6] Additional Minor Diterpene Glycosides from Stevia rebaudiana Bertoni
Prakash, Indra
Chaturvedula, Venkata Sai Prakash
MOLECULES, 2013, 18 (11) : 13510 - 13519
[7] A New Diterpene Glycoside: 15α-Hydroxy-Rebaudioside M Isolated from Stevia rebaudiana
Prakash, Indra
Ma, Gil
Bunders, Cynthia
Devkota, Krishna P.
Charan, Romila D.
Ramirez, Catherine
Snyder, Tara M.
Priedemann, Christopher
NATURAL PRODUCT COMMUNICATIONS, 2015, 10 (07) : 1159 - 1161
[8] CHEMICAL STUDIES ON SWEET DITERPENE-GLYCOSIDES OF STEVIA-REBAUDIANA - CONVERSION OF STEVIOSIDE INTO REBAUDIOSIDE-A
KANEDA, N
KASAI, R
YAMASAKI, K
TANAKA, O
CHEMICAL & PHARMACEUTICAL BULLETIN, 1977, 25 (09) : 2466 - 2467
[9] ACCUMULATION OF STEVIOSIDE AND REBAUDIOSIDE A IN CALLUS-CULTURE OF STEVIA-REBAUDIANA BERTONI
HSING, YI
SU, WF
CHANG, WC
BOTANICAL BULLETIN OF ACADEMIA SINICA, 1983, 24 (02): : 115 - 119
[10] Extraction of rebaudioside-A by sonication from Stevia rebaudiana Bertoni leaf and decolorization of the extract by polymers
Gasmalla, Mohammed Abdalbasit A.
Yang, Ruijin
Hua, Xiao
JOURNAL OF FOOD SCIENCE AND TECHNOLOGY-MYSORE, 2015, 52 (09): : 5946 - 5953

← 1 2 3 4 5 →