Two-stage equilibrium model for a coal gasifier to predict the accurate carbon conversion in hydrogen production

The performance of the Texaco gasifier in hydrogen production was studied numerically. To estimate the accurate carbon conversion, a two-stage equilibrium model was proposed. In the proposed model, the two reactions which determined the carbon conversion were separated from other vapor-vapor reactions. The governing equations of the proposed model were derived and a self-consistent method was developed to solve the governing equations. The %AAD of the calculated carbon conversions from the measured values was 2.89 and that of the calculated gas production rate was 0.64. Calculated gas compositions showed a fairly good agreement with the experimental ones for commercial scale plants. It was found that the chemical reactions that occurred in the Texaco gasifier possess a mechanism for keeping the carbon conversion close to unity against a wide variation in the H2O to coal ratios. (C) 2008 Elsevier Ltd. All rights reserved.