Novel lipase-catalyzed ring-opening copolymerization of oxiranes and succinic anhydride forming polyesters bearing functional groups

被引：0
|
作者：
Matsumura, S [1 ]
Okamoto, T [1 ]
Tsukada, K [1 ]
Toshima, K [1 ]
机构：
[1] Keio Univ, Fac Sci & Technol, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 1998年 / 19卷 / 06期
关键词：
D O I：
10.1002/(SICI)1521-3927(19980601)19:6<295::AID-MARC295>3.0.CO;2-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Oxiranes, such as glycidyl phenyl ether (GPE) and benzyl glycidate (BG), were copolymerized with succinic anhydride (SA) by lipase at a temperature between 60 and 80 degrees C to yield the corresponding polyesters bearing carboxyl or phenyl groups. Bulk polymerization, especially at the temperature of 80 degrees C, and preferably using porcine pancreatic lipase gave biodegradable polyesters with a molecular weight greater than 5000.
引用
收藏
页码：295 / 298
页数：4
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