The Proton Affinity and Gas-Phase Basicity of Sulfur Dioxide

被引：28
|
作者：
de Petris, Giulia [1 ]
Cartoni, Antonella [1 ]
Rosi, Marzio [2 ,3 ]
Barone, Vincenzo [4 ]
Puzzarini, Cristina [5 ]
Troiani, Anna [1 ]
机构：
[1] Univ Roma La Sapienza, Dipartimento Chim & Tecnol Farm, I-00185 Rome, Italy
[2] Univ Perugia, Dipartimento Ingn Civile & Ambientale, I-06123 Perugia, Italy
[3] CNR, ISTM, I-06123 Perugia, Italy
[4] Scuola Normale Super Pisa, I-56126 Pisa, Italy
[5] Univ Bologna, Dipartimento G Ciamician, I-40126 Bologna, Italy
来源：
CHEMPHYSCHEM | 2011年 / 12卷 / 01期
关键词：
basicity; mass spectrometry; proton transfer; sulfur dioxide; thermochemistry; COUPLED ELECTRON-TRANSFER; OXYGEN-CENTERED RADICALS; ACTIVATION; METHANE; SCALE; WATER; ATOM; THERMOCHEMISTRY; MOLECULES;
D O I：
10.1002/cphc.201000920
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Going down the steps: New gas-phase experiments and theoretical calculations revise significantly downward the proton affinity and gas-phase basicity of sulfur dioxide (see picture). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：112 / 115
页数：4
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