Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems .3. Zigzag one-dimensional chains

被引:4
|
作者
Tadokoro, M
Isobe, K
Nakasuji, K
机构
[1] OSAKA CITY UNIV,FAC SCI,DEPT MAT SCI,SUMIYOSHI KU,OSAKA 558,JAPAN
[2] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN
关键词
D O I
10.1080/10587259608033675
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure of [Ni(Hbim)(3)]((Pr4N)-Pr-n). MeOH (1) (Hbim(-) = mono- deprotonated 2,2'-biimidazolate and (Pr4N+)-Pr-n = tetra-n-propyl-ammonium cation) has been determined. The structure was consists of Ni(II) centers hexacoordinated by three 2,2'-biimidazolate (Hbim(-)) ligands in an octahedral arrangement. Complex 1 possesses an intermolecular hydrogen bonding structure of zigzag one-dimensional chains in which two of the three Hbim(-) ligands connect the metal complex units.
引用
收藏
页码:213 / 216
页数:4
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