(±)-1,1′-Binaphthalene-2,2′-diol-derived phosphoric diester: immobilization on polyethylene glycol support and application in the Pudovik reaction

被引：4

作者：

Beletskaya, I. P. ^{[1
]}

Patrikeeva, L. S. ^{[1
,2
]}

Lamaty, F. ^{[2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[2] Univ Montpellier 2, Max Mousseron Inst Biomol IBMM, F-34095 Montpellier 05, France

来源：

RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

(+/-)-BINOL; phosphoric acids; polyethylene glycol; alpha-aminophosphonates; the Pudovik reaction; recyclization; ALPHA-AMINO PHOSPHONATES; ASYMMETRIC-SYNTHESIS; EFFICIENT SYNTHESIS; CLICK CHEMISTRY; ORGANOPHOSPHORUS COMPOUNDS; STEREOSELECTIVE-SYNTHESIS; BINOL COMPLEXES; DERIVATIVES; PHOSPHITE; AMINOPHOSPHONATES;

D O I：

10.1007/s11172-011-0364-8

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(+/-)-1,1'-Binaphthalene-2,2'-diol (BINOL) was immobilized on polyethylene glycol (PEG) by means of triazole linkers, which were constructed by the [3+2] cycloaddition between azide and ethynyl fragments, preliminary incorporated into the molecules of these reactants. Treatment of these BINOL derivatives with phosphorus oxychloride leads to the corresponding PEG-immobilized 1,1'-binaphthalene-2,2'-diylphosphoric acids. The latter efficiently catalyze the Pudovik reaction and can be reused without loss of catalytic activity.

引用

页码：2370 / 2374

页数：5

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