A two-dimensional coordination polymer containing linear trinuclear copper(II) clusters

被引：4
|
作者：
Wang, Ji-Jiang [1 ]
Zhang, Bo [1 ]
Shu, Hui-Ming [1 ]
Du, Chuan-Qin [1 ]
Hu, Huai-Ming [1 ]
机构：
[1] NW Univ Xian, Dept Chem, Xian 710069, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807034927
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title coordination polymer, poly[diaqua(1,10-phenanthroline)(mu(3)-pyrazole-3,5-dicarboxylato)tricopper(II)], [Cu-3-(C5HN2O4)(2)(Cl2H8N2)(2)(H2O)(2)](n), was hydrothermally synthesized and structurally characterized. It consists of linear trinuclear copper(II) clusters of [Cu-3(pdc)(2)(phen)(2)(H2O)(2)] units (H(3)pdc = pyrazole-3,5-dicarboxylic acid and phen = 1,10-phenanthroline), in which two pdc(3-) ligands chelate three Cu-II ions with the central Cu-II ion on an inversion center. An infinite two-dimensional sheet structure is constructed by connecting adjacent linear trinuclear copper(II) units through coordination bonds between the central Cu-II atom and an O atom of the carboxylate group coordinated to the terminal Cu-II atom from the pdc(3-) ligand.
引用
收藏
页码：M2190 / U1511
页数：12
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