A new approach to the synthesis of 2,2′-diamino-1,1′-binaphthyl

被引：0

作者：

Tan, DM ^{[1
]}

Wu, JA ^{[1
]}

Wang, B ^{[1
]}

Xu, ZL ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Dept Appl Chem, Guangzhou 510275, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 21卷 / 01期

关键词：

2-naphthylamine; 2,2 '-diamino-1,1 '-binaphthyl; cupric chloride; oxidative coupling;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The coupling of 2-naphthylamine with 1.5 eq. of CuCl2. 2H(2)O in methanol at room temperature results in the complex of 2,2'-diamino-1,1'-binaphthyl (1) with CuCl2, which yields 56% of free 1 after filtration and decomposition in boiling water and aqueous NH3 in turn.

引用

页码：64 / 65

页数：2

共 9 条

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