Deformable homeotropic nematic droplets in a magnetic field

被引:7
|
作者
Otten, Ronald H. J. [1 ,2 ]
van der Schoot, Paul [1 ,3 ]
机构
[1] Eindhoven Univ Technol, Theory Polymers & Soft Matter & Eindhoven Polyme, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands
[3] Univ Utrecht, Inst Theoret Phys, NL-3584 CE Utrecht, Netherlands
来源
JOURNAL OF CHEMICAL PHYSICS | 2012年 / 137卷 / 15期
关键词
drops; elastic deformation; elasticity; elongation; liquid structure; magnetic field effects; magnetic susceptibility; nematic liquid crystals; phase diagrams; POLYMER LIQUID-CRYSTAL; PLATE-LIKE PARTICLES; INTERFACIAL-TENSION; FINE-STRUCTURE; SUSPENSIONS; DEFECTS; PHASE; TRANSITION; TACTOIDS;
D O I
10.1063/1.4756946
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present a Frank-Oseen elasticity theory for the shape and structure of deformable nematic droplets with homeotropic surface anchoring in the presence of a magnetic field. Inspired by recent experimental observations, we focus on the case where the magnetic susceptibility is negative, and find that small drops have a lens shape with a homogeneous director field for any magnetic-field strength, whereas larger drops are spherical and have a radial director field, at least if the magnetic field is weak. For strong magnetic fields the hedgehog configuration transforms into a split-core line defect that, depending on the anchoring strength, can be accompanied by an elongation of the tactoid itself. We present a three-dimensional phase diagram that shows the tactoid shape and director field for a given anchoring strength, tactoid size, and magnetic-field strength. Our findings rationalize the different shapes and structures that recently have been observed experimentally for nematic droplets found in dispersions of gibbsite platelets in two types of solvent. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4756946]
引用
收藏
页数:12
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