Novel chiral recognition beyond the limitation due to the law of mass action: highly enantioselective chiral sensing based on non-linear response in phase transition events

被引：6

作者：

Hirose, Keiji ^{[1
]}

Yachi, Yuka ^{[1
]}

Tobe, Yoshito ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Div Frontier Mat Sci, Osaka 5608531, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 23期

基金：

日本科学技术振兴机构;

关键词：

AZOPHENOLIC CROWN-ETHERS; VISUAL ENANTIOMERIC RECOGNITION; AMINO-ACID; PSEUDO-18-CROWN-6; ETHER; ABSOLUTE-CONFIGURATION; COMPLEXATION; POLYMERIZATION; ASSIGNMENT; SEPARATION; BEHAVIOR;

D O I：

10.1039/c1cc11731a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on non-linear response in phase transition events exhibiting a sharp transmittance change, an intelligent chiral sensor capable of chirality amplification in aqueous media was designed and constructed as poly(N-isopropylacrylamide) having chiral pseudo-18-crown-6. Both sensitivity and selectivity of the sensor surmount the limitation due to the law of mass action.

引用

页码：6617 / 6619

页数：3