Two new 3D lanthanide metal-organic frameworks constructed from nitrilotriacetate and oxalate ligands

被引：3
|
作者：
Yang, Qing-Feng [1 ]
Cui, Xiao-Bing [2 ,3 ]
Chen, Yan [2 ,3 ]
Wang, Zheng [1 ]
Yu, Jie-Hui [2 ,3 ]
Xu, Ji-Qing [2 ,3 ]
Wang, Tie-Gang [2 ,3 ]
机构：
[1] Ningxia Univ, Key Lab Energy Resources & Chem Engn, Ningxia 750021, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130021, Jilin, Peoples R China
[3] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130021, Jilin, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Lanthanide; Metal-organic frameworks; Topology; Magnetic analyses; COORDINATION POLYMERS; REVERSIBLE DEHYDRATION; HYDROTHERMAL SYNTHESIS; RETICULAR CHEMISTRY; NETWORK; LUMINESCENCE; CAVITIES; DESIGN; SERIES;
D O I：
10.1016/j.inoche.2010.11.027
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two isomorphous three-dimensional lanthanide metal-organic frameworks, K[Ln(2)(NTA)(ox)(2)(H2O)(2)]center dot 3H(2)O (Ln = Pr (1) and Gd (2), NTA = nitrilotriacetate, ox = oxalate) have been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectroscopy, single-crystal X-ray diffraction, thermogravimetric analysis (TGA) and magnetic analyses. The 3D frameworks of compounds 1 and 2 possess three topologically nonequivalent 4-connected nodes synchronously and exhibit unprecedented (6(5).8) (4(3).6(3))(4.6(5)) topologies. Variable-temperature magnetic susceptibility measurements for complexes 1 and 2 indicate there exist antiferromagnetic interactions between magnetic centers. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：320 / 323
页数：4
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