A chiral phosphorous derivatizing agent for the determination of the enantiomeric excess of chiral alcohols, amines by 31P NMR

被引：0

作者：

Li, KY

Zhou, ZH

Yeung, CH

Tang, CC

机构：

[1] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

[2] Hong Kong Polytech Univ, Lab Chiral Technol, Hong Kong, Hong Kong, Peoples R China

[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2001年 / 12卷 / 10期

关键词：

chiral phosphorous; derivation; chiral alcohols; chiral amines; enantiomeric excess; asymmetric induction;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral phosphorous derivatizing agent prepared from PCl3 and (S)-BINOL was described. It is used to determine the enantiomeric excess of chiral alcohols and amines by (31)p NMR.

引用

页码：907 / 908

页数：2

共 50 条

[1] A Chiral Phosphorous Derivatizing Agent for the Determination of the Enantiomeric Excess of Chiral Alcohols, Amines by 31P NMR
Kang Ying LI1
Chinese Chemical Letters, 2001, (10) : 907 - 908
[2] An efficient chiral phosphorus derivatizing agent for the determination of the enantiomeric excess of chiral alcohols and amines by 31P NMR spectroscopy
Li, KY
Zhou, ZH
Chan, ASC
Tang, CC
HETEROATOM CHEMISTRY, 2002, 13 (01) : 93 - 95
[3] P*-chiral phosphapalladacycle as derivatizing agent for enantiomeric purity determination of α-amino acids by means of 31P NMR spectroscopy
Dunina, VV
Gorunova, ON
Livantsov, MV
Grishin, YK
TETRAHEDRON-ASYMMETRY, 2000, 11 (14) : 2907 - 2916
[4] New chiral organophosphorus derivatizing agent for the determination of enantiomeric composition of chloro- and bromohydrins by 31P NMR spectroscopy
Reymond, S
Brunel, JM
Buono, G
TETRAHEDRON-ASYMMETRY, 2000, 11 (06) : 1273 - 1278
[5] Novel chiral derivatizing isothiocyanate-based agent for the enantiomeric excess determination of amines
Sabot, Cyrille
Mosser, Michel
Antheaume, Cyril
Mioskowski, Charles
Baati, Rachid
Wagner, Alain
CHEMICAL COMMUNICATIONS, 2009, (23) : 3410 - 3412
[6] First principles design of derivatizing agent for direct determination of enantiomeric purity of chiral alcohols and amines by NMR spectroscopy
Orlov, Nikolay V.
Ananikov, Valentine P.
CHEMICAL COMMUNICATIONS, 2010, 46 (18) : 3212 - 3214
[7] Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR
Chauvin, Anne-Sophie
Alexakis, Alexandre
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2
[8] Determination of the absolute configuration of chiral cyclic alcohols using diamine derivatizing agents by 31P NMR spectroscopy
Chauvin, Anne-Sophie
Bernardinelli, Gerald
Alexakis, Alexandre
TETRAHEDRON-ASYMMETRY, 2006, 17 (15) : 2203 - 2209
[9] ALPHA-PHENYLETHYLAMINE BASED CHIRAL PHOSPHOLIDINES - NEW AGENTS FOR THE DETERMINATION OF THE ENANTIOMERIC EXCESS OF CHIRAL ALCOHOLS, AMINES AND THIOLS BY MEANS OF P-31 NMR
HULST, R
DEVRIES, NK
FERINGA, BL
TETRAHEDRON-ASYMMETRY, 1994, 5 (04) : 699 - 708
[10] Determination of the enantiomeric excess of chiral carboxylic acids by 31P NMR with C2 symmetrical diamines
Alexakis, A
Chauvin, AS
TETRAHEDRON-ASYMMETRY, 2001, 12 (10) : 1411 - 1415

← 1 2 3 4 5 →