Sterically crowded monomeric neutral bis(benzamidinato) compounds of aluminium, [PhC(NSiMe(3))(2)](2)AlX (X=Cl, H); X-ray crystal structure of [PhC(NSiMe(3))(2)]2AlH

被引：40

作者：

Duchateau, R ^{[1
]}

Meetsma, A ^{[1
]}

Teuben, JH ^{[1
]}

机构：

[1] UNIV GRONINGEN,CTR CATALYSIS & SYNTH,DEPT CHEM,9747 AG GRONINGEN,NETHERLANDS

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000223

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

AlCl3 reacts with [PhC(NSiMe(3))(2)]Li(OEt(2)) to afford the bis(N,N'-bis(trimethylsilyl)benzamidinato)aluminium chloro compound which, on treatment with KBEt(3)H, yields the structurally characterized monomeric hydride derivative, [PhC(NSiMe(3))(2)]2AlH, whose reactivity towards unsaturated hydrocarbons illustrates the low electrophilicity of the aluminium and high basic character of the hydride group.

引用

页码：223 / 224

页数：2

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