Resolution of chiral polyoxoanion[P2Mo18O62]6- with histidine

被引：37
|
作者：
Liu, Ding [1 ]
Tan, Hua-Qiao [1 ]
Chen, Wei-Lin [1 ]
Li, Yang-Guang [1 ]
Wang, En-Bo [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 07期
基金：
中国国家自然科学基金;
关键词：
AQUEOUS ALKALINE-SOLUTION; POLYOXOMETALATE CLUSTERS; CRYSTAL-STRUCTURE; 3D ARCHITECTURES; NMR-SPECTROSCOPY; BUILDING-BLOCKS; AMINO-ACIDS; ANIONS; FRAMEWORK;
D O I：
10.1039/c001160f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The classical Dawson-type racemic polyoxoanions [P2Mo18O62](6-) have been separated in aqueous solution with L,D-histidine, respectively. Two enantiomerically pure compounds: H-3(L-HC6H9N3O2)(3)[P2Mo18O62]center dot 20H(2)O (1a), H-3(D-HC6H9N3O2)(3)[P2Mo18O62]center dot 20H(2)O (1b), have been synthesized.
引用
收藏
页码：2044 / 2046
页数：3
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