Transport and spectroscopic studies of the effects of fullerene structure on the efficiency and lifetime of polythiophene-based solar cells

Time-dependent measurements of both power conversion efficiency and ultraviolet-visible absorption spectroscopy have been observed for solar cell blends containing the polymer poly(3-hexylthiophene-2,5-diyl) (P3HT) with two different functionalized C-60, electron acceptor molecules: commercially available [6,6]-phenyl C-61 butyric acid methyl ester (PCBM) or [6,6]-phenyl C-61 butyric acid octadecyl ester (PCBOD) produced in this laboratory. Efficiency was found to decay with an exponential time dependence, while spectroscopic features show saturating exponential behavior. Time constants extracted from both types of measurements showed reasonable agreement for samples produced from the same blend. In comparison to the PCBM samples, the stability of the PCBOD blends was significantly enhanced, while both absorption and power conversion efficiency were decreased. (C) 2012 Elsevier B.V. All rights reserved.