Table of periodic properties of fullerenes based on structural parameters

被引:10
|
作者
Torrens, F [1 ]
机构
[1] Univ Valencia, Inst Ciencia Mol, E-46100 Valencia, Spain
关键词
D O I
10.1021/ci030029x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The periodic table (PT) of the elements suggests that hydrogen could be the origin of everything else. The construction principle is an evolutionary process that is formally similar to those of Darwin and Oparin. The Kekule structure count and permanence of the adjacency matrix of fullerenes are related to structural parameters involving the presence of contiguous pentagons p, q and r. Let p be the number of edges common to two pentagons, q the number of vertices common to three pentagons, and r the number of pairs of nonadjacent pentagon edges shared between two other pentagons. Principal component analysis (PCA) of the structural parameters and cluster analysis (CA) of the fullerenes permit classifying them and agree. A PT of the fullerenes is built based on the structural parameters, PCA and CA. The periodic law does not have the rank of the laws of physics. (1) The properties of the fullerenes are not repeated; only, and perhaps, their chemical character. (2) The order relationships are repeated, although with exceptions. The proposed statement is the following: The relationships that any fullerene p has with its neighbor p + 1 are approximately repeated for each period.
引用
收藏
页码:60 / 67
页数:8
相关论文
共 50 条
  • [1] Table of periodic properties of fullerenes based on structural parameters
    Torrens, F
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2004, 709 (1-3): : 135 - 142
  • [2] Structural and electronic properties of C and BN nanotubes based on periodic fullerenes: A density functional theory study
    Majidi, Roya
    Ghorbani, Modjtaba
    FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2017, 25 (04) : 265 - 268
  • [3] From Periodic Properties to a Periodic Table Arrangement
    Besalu, Emili
    JOURNAL OF CHEMICAL EDUCATION, 2013, 90 (08) : 1009 - 1013
  • [4] Glass properties and the periodic table
    Huggins, ML
    Sun, KH
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1944, 27 (01) : 13 - 17
  • [5] Pertechnetates - A Structural Study Across the Periodic Table
    Strub, Erik
    Groedler, Dennis
    Zaratti, Daniele
    Yong, Clarence
    Duennebier, Lisa
    Bazhenova, Sonja
    Roca Jungfer, Maximilian
    Breugst, Martin
    Zegke, Markus
    CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (26)
  • [6] Structural and electronic properties of new α-graphyne-based carbon fullerenes
    Enyashin, AN
    Sofronov, AA
    Makurin, YN
    Ivanovskii, AL
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2004, 684 (1-3): : 29 - 33
  • [7] New structural parameters of fullerenes for principal component analysis
    F. Torrens
    Theoretical Chemistry Accounts, 2003, 110 : 371 - 376
  • [9] New structural parameters and permanents of adjacency matrices of fullerenes
    Jiang, Shan
    Liang, Heng
    Bai, Fengshan
    MATCH-COMMUNICATIONS IN MATHEMATICAL AND IN COMPUTER CHEMISTRY, 2006, 56 (01) : 131 - 139
  • [10] REGULARITIES OF STARK PARAMETERS ALONG THE PERIODIC-TABLE
    PURIC, J
    CUK, M
    DIMITRIJEVIC, MS
    LESAGE, A
    ASTROPHYSICAL JOURNAL, 1991, 382 (01): : 353 - 357