A cationic palladium(II) complex-catalyzed Diels-Alder reaction

被引：42
|
作者：
Oi, S [1 ]
Kashiwagi, K [1 ]
Inoue, Y [1 ]
机构：
[1] Tohoku Univ, Grad Sch Engn, Dept Chem Mat, Sendai, Miyagi 9808579, Japan
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 34期
关键词：
D O I：
10.1016/S0040-4039(98)01288-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A cationic palladium(II) complex, [PdL2(RCN)(2)](BF4)(2) has been found to catalyze the Diels-Alder reaction of alpha, beta-unsaturated carbonyl compounds with dienes, affording the corresponding cycloadducts in good yields. Excellent enantioselectivity can be achieved in the reaction of N-acryloyloxazolidinone and cyclopentadiene by use of a chiral ligand, BINAP. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6253 / 6256
页数：4
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