The green and effective oxidation of alcohols to carboxylic acids with molecular oxygen via biocatalytic reaction

被引：34
|
作者：
Hirano, Jun-ichiro [1 ]
Miyamoto, Kenji [1 ]
Ohta, Hiromichi [1 ]
机构：
[1] Keio Univ, Dept Biosci & Informat, Yokohama, Kanagawa 2238522, Japan
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 07期
关键词：
alcohol oxidation; molecular oxygen; biocatalyst; green chemistry; regeneration of cofactor;
D O I：
10.1016/j.tetlet.2007.12.032
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A clean and effective alcohol oxidizing system using three enzymes has been developed. Regeneration of NAD(+) by NADH oxidase with molecular oxygen enabled to oxidize alcohols to carboxylic acids in good yield under mild conditions (25 degrees C, 1 atm). (c) 2007 Published by Elsevier Ltd.
引用
收藏
页码：1217 / 1219
页数：3
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