Spectroscopic study of the C(3)1Σ+ ← X1Σ+ and c(2)3Σ+ ← X1Σ+ transitions in KCs molecule

被引：12
|
作者：
Szczepkowski, Jacek [1 ]
Grochola, Anna [1 ]
Kowalczyk, Pawel [2 ]
Jastrzebski, Wlodzimierz [1 ]
机构：
[1] Polish Acad Sci, Inst Phys, Al Lotnikow 32-46, PL-02668 Warsaw, Poland
[2] Univ Warsaw, Inst Expt Phys, Fac Phys, Ul Pasteura 5, PL-02093 Warsaw, Poland
来源：
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 2018年 / 204卷
关键词：
Laser spectroscopy; Alkali dimers; Electronic states; Potential energy curves; POLARIZATION LABELING SPECTROSCOPY; STATE; UNCERTAINTY; LIFETIME;
D O I：
10.1016/j.jqsrt.2017.09.013
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
We present an experimental investigation of the C(3)(1)Sigma(+) and c(2)(3)Sigma(+) states of KCs using two-colour polarisation labelling spectroscopy (PLS) technique. Pointwise potential energy curves are generated for both states using the inverted perturbation approach (IPA) method. The experimental pointwise potentials and molecular constants T-e, omega(e), and R-e are compared with theoretical calculations. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：131 / 137
页数：7
相关论文
共 50 条
  • [1] Theoretical investigation of the A1Π-X1Σ+, B1Σ+-X1Σ+, C1Σ+-X1Σ+, and E1Π-X1Σ+ transitions of the CO molecule
    Khalil, Malathe
    Mahmoud, Salman
    Brady, Ryan P.
    Almehairbi, Mubarak
    Gacesa, Marko
    Yurchenko, Sergei N.
    Tennyson, Jonathan
    Al Ghaferi, Amal
    El-Kork, Nayla
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2025, 27 (05) : 2783 - 2801
  • [2] Ab initio relativistic treatment of the a3Π - X1Σ+, a′3Σ+ - X1Σ+ and A1Π - X1Σ+ systems of the CO molecule
    Mosyagin, N. S.
    Oleynichenko, A., V
    Zaitsevskii, A.
    Kudrin, A., V
    Pazyuk, E. A.
    Stolyarov, A., V
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2021, 263 (263):
  • [3] High resolution spectra of the AuF D1Σ+-X1Σ+ and C1Π-X1Σ+ transitions
    Knurr, Benjamin J.
    Butler, Elissa K.
    Varberg, Thomas D.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [4] Spectroscopic properties of BCl (X1Σ+, a3Π, A1Π) molecule
    Liu Hui
    Xing Wei
    Shi De-Heng
    Sun Jin-Feng
    Zhu Zun-Lue
    ACTA PHYSICA SINICA, 2014, 63 (12)
  • [5] Generalized Schur Numbers for x1 + x2 + c=3x3
    Kezdy, Andre E.
    Snevily, Hunter S.
    White, Susan C.
    ELECTRONIC JOURNAL OF COMBINATORICS, 2009, 16 (01):
  • [6] Benchmark configuration interaction spectroscopic constants for X1Σg+ C2 and X1Σ+ CN+
    Leininger, ML
    Sherrill, CD
    Allen, WD
    Schaefer, HF
    JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (16): : 6717 - 6721
  • [7] Spectroscopic parameters and molecular constants of HI(X1Σ+), DI(X1Σ+) and TI(X1Σ+) isotope molecules
    Zhang Xiao-Niu
    Shi De-Heng
    Zhu Zun-Lue
    Sun Jin-Feng
    CHINESE PHYSICS B, 2010, 19 (12)
  • [8] The (1)1Π, (2)1Σ+ → X1Σ+ transitions of LaF
    Bernard, A
    Effantin, C
    d'Incan, J
    Vergès, J
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2000, 202 (01) : 163 - 165
  • [9] Distinct Rado Numbers for x1 + x2 + c = x3
    Flint, Donna
    Lowery, Bradley
    Schaal, Daniel
    ARS COMBINATORIA, 2013, 110 : 331 - 342
  • [10] MRCI study on the spectroscopic parameters and molecular constants of the X1Σ+, a3Σ+, A1Π and C1Σ- electronic states of the SiO molecule
    Shi, Deheng
    Li, Wentao
    Sun, Jinfeng
    Zhu, Zunlue
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 87 : 96 - 105
12345