The giant Muruntau gold deposit geologic, geochronologic, and fluid inclusion constraints on ore genesis

We reinterpret the regional geologic setting of the giant Muruntau gold deposit and report new 40Ar/39Ar isotope age determinations and a laser Raman microprobe analysis of fluid inclusions. New 40Ar/39Ar isotope age determinations of hydrothermal sericite seh ages to gold-stage quartz veins are in excellent agreement with older Rb-Sr dates oil auriferous quartz veins. They suggest Triassic sericite formation at 245 and 220 Ma, some 30 m.y later than subjacent felsic intrusions as defined by Rb-Sr data. These dates call into question the role of magmatic fluid, metal, and heat input. Indeed, the Rb-Sr pluton ages may be a reflection of hydrothermal activity. rather than cooling from magmatic conditions. The Muruntau deposit is situated adjacent to a major rift, which has been periodically active from the Devonian to the Tertiary and has accumulated a substantial thickness of chemical, volcaniclastic, and elastic sediments, including red beds and evaporites. We infer that the Muruntau deposit is so large because of the presence of a major source of reduced sulfur in these nearby evaporitic sediments, via thermochemical sulfate reduction. Some support for the role of reduced sulfur is provided by the presence of detectable H2S in fluid inclusions from late-stage auriferous quartz veins. Reduced sulfur-rich fluids could have been focused into the depositional site along major northeast-trending structures, which have influenced rift-basin architecture as recently as the Jurassic. Oxidation could, therefore, be an important ore-precipitating mechanism. A change from early CH4- to later syngold CO2-dominant fluid inclusions may be an indication of this process. We reinterpret the regional geologic setting of the giant Muruntau gold deposit and report new 40Ar/39Ar isotope age determinations and a laser Raman microprobe analysis of fluid inclusions. New 40Ar/39Ar isotope age determinations of hydrothermal sericite seh ages to gold-stage quartz veins are in excellent agreement with older Rb-Sr dates oil auriferous quartz veins. They suggest Triassic sericite formation at 245 and 220 Ma, some 30 m.y later than subjacent felsic intrusions as defined by Rb-Sr data. These dates call into question the role of magmatic fluid, metal, and heat input. Indeed, the Rb-Sr pluton ages may be a reflection of hydrothermal activity. rather than cooling from magmatic conditions. The Muruntau deposit is situated adjacent to a major rift, which has been periodically active from the Devonian to the Tertiary and has accumulated a substantial thickness of chemical, volcaniclastic, and elastic sediments, including red beds and evaporites. We infer that the Muruntau deposit is so large because of the presence of a major source of reduced sulfur in these nearby evaporitic sediments, via thermochemical sulfate reduction. Some support for the role of reduced sulfur is provided by the presence of detectable H2S in fluid inclusions from late-stage auriferous quartz veins. Reduced sulfur-rich fluids could have been focused into the depositional site along major northeast-trending structures, which have influenced rift-basin architecture as recently as the Jurassic. Oxidation could, therefore, be an important ore-precipitating mechanism. A change from early CH4- to later syngold CO2-dominant fluid inclusions may be an indication of this process.