Self-assembly of a pseudo-tetrahedral Zn(II) complex with a chiral reduced Schiff base into a helical superstructure

被引：18
|
作者：
Muppidi, VK [1 ]
Zacharias, PS [1 ]
Pal, S [1 ]
机构：
[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 06期
关键词：
zinc(II) complex; tetrahedral; chiral; crystal structure; helical;
D O I：
10.1016/j.inoche.2005.03.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A pseudo-tetrahedral Zn(II) complex with an N,O-donor chiral reduced Schiff base N-(2-hydroxy-5-nitrobenzyl)-(R)-alpha-methylbenzylamine (HL) crystallize in the non-centrosymmetric space group P3(1). The [ZnL2] molecules having the Delta configuration assemble via intermolecular N-H center dot center dot center dot O and C-H center dot center dot center dot O interactions into a right-handed 3(1) helix. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：543 / 547
页数：5
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