Ruthenium-catalyzed allylic substitution of allylic cyclic carbonates

被引：19
|
作者：
Kang, SK
Kim, DY
Hong, RK
Ho, PS
机构：
[1] Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus
来源：
SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 17期
关键词：
D O I：
10.1080/00397919608004631
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh(3))(2)Cl (5 mol %) afforded (E)-allylic alcohol and erythro-beta-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to x-allyl ruthenium complex.
引用
收藏
页码：3225 / 3235
页数：11
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