Kinetics and mechanism of Ru(VIII)-catalysed oxidation of methyl glycol by Ce(IV) in perchloric acid medium

被引：0

作者：

Singh, SB ^{[1
]}

Singh, D ^{[1
]}

Sahay, VP ^{[1
]}

Prasad, M ^{[1
]}

Prasad, J ^{[1
]}

机构：

[1] Magadh Univ, Dept Chem, Bodh Gaya 824234, India

来源：

ASIAN JOURNAL OF CHEMISTRY | 1999年 / 11卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of ruthenium(VIII) catalysed oxidation of methyl glycol by eerie perchlorate in perchloric acid medium have been studied. The reaction exhibits zero-order kinetics in Ce(IV) and first order rate dependence with respect to each of methyl glycol and Ru(VIII). Negligible effect of [H+] and ionic strength of the medium has been observed. A suitable mechanism, consistent with the observed kinetic data, is proposed.

引用

页码：663 / 665

页数：3

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