Analysis of the properties of metallorganic compounds containing the Fe3+ nanoprobes

被引：0

作者：

Shapovalov, Vladimir V. ^{[1
]}

Shapovalov, Vladimir A. ^{[2
]}

Aksimentyeva, Olena, I ^{[3
]}

Shavrov, Vladimir G. ^{[4
]}

Koledov, Victor V. ^{[4
]}

Valkov, Victor, I ^{[2
]}

机构：

[1] Math Amer, New York, NY USA

[2] A Galkin Donetsk Inst Phys & Engn, Nauki Ave 46, UA-03680 Kiev, Ukraine

[3] Ivan Franko Natl Univ Lviv, Lvov, Ukraine

[4] RAS, Kotelnikov Inst Radioengn & Elect IRE, Moscow, Russia

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2021年 / 718卷 / 01期

关键词：

Complexes with magnetic probes; electron spin resonance (ESR); metalloproteins; polymers; X-ray structure analysis;

D O I：

10.1080/15421406.2020.1861523

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coordination compounds containing the Fe3+ ions like sodium salt Na[FeO6(C10H8N)(3)], kaolinite Al-2[Si2O5].(OH)(4), metalloproteins (Ferritin, Maltofer, and Ferrum Lek) find a wide application. The analysis of the properties of these compounds has demonstrated a developed crystal structure. The diffractogram of Ferritin included an amorphous component. Within the temperature range of 4.2-300 K, all the compounds are characterized by transformation and mutual transfer of the lines of electron paramagnetic resonance spectrum of the Fe3+ ions (EPR). This fact allows estimation of a dynamical characteristic of the nearest neighbor environment of Fe3+.

引用

页码：62 / 68

页数：7

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