Clean hydrogen production with the Cu-Cl cycle - Progress of international consortium, I: Experimental unit operations

被引：61

作者：

Naterer, G. F. ^{[1
]}

Suppiah, S. ^{[2
]}

Stolberg, L. ^{[2
]}

Lewis, M. ^{[3
]}

Ferrandon, M. ^{[4
]}

Wang, Z. ^{[1
]}

Dincer, I. ^{[1
]}

Gabriel, K. ^{[1
]}

Rosen, M. A. ^{[1
]}

Secnik, E. ^{[1
]}

Easton, E. B. ^{[5
]}

Trevani, L. ^{[5
]}

Pioro, I. ^{[6
]}

Tremaine, P. ^{[7
]}

Lvov, S. ^{[8
]}

Jiang, J. ^{[9
]}

Rizvi, G. ^{[1
]}

Ikeda, B. M. ^{[6
]}

Lu, L. ^{[6
]}

Kaye, M. ^{[6
]}

Smith, W. R. ^{[5
]}

Mostaghimi, J. ^{[10
]}

Spekkens, P. ^{[11
]}

Fowler, M. ^{[12
]}

Avsec, J. ^{[13
]}

机构：

[1] Univ Ontario Inst Technol, Fac Engn & Appl Sci, Oshawa, ON L1H 7K4, Canada

[2] Atom Energy Canada Ltd, Hydrogen Isotopes Technol Branch, Chalk River, ON K0J 1J0, Canada

[3] Cemeglas Inc, The Villages, FL 32162 USA

[4] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[5] Univ Ontario Inst Technol, Fac Sci, Oshawa, ON L1H 7K4, Canada

[6] Univ Ontario Inst Technol, Fac Energy Syst & Nucl Sci, Oshawa, ON L1H 7K4, Canada

[7] Univ Guelph, Dept Chem, Guelph, ON N1G 2W1, Canada

[8] Penn State Univ, Dept Mat Sci & Engn, Dept Energy & Mineral Engn, University Pk, PA 16802 USA

[9] Univ Western Ontario, Dept Elect & Comp Engn, London, ON N6A 5B9, Canada

[10] Univ Toronto, Dept Mech & Ind Engn, Toronto, ON M5S 3E5, Canada

[11] Ontario Power Generat, Pickering, ON L1V 2R5, Canada

[12] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada

[13] Univ Maribor, Fac Energy Technol, Krshko 8270, Slovenia

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2011年 / 36卷 / 24期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Hydrogen production; Thermochemical copper-chlorine cycle; Electrolysis; Spray drying; Hydrolysis; Decomposition;

D O I：

10.1016/j.ijhydene.2011.08.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Advancement of the thermochemical copper-chlorine (Cu-Cl) cycle for hydrogen production is reviewed and discussed in this paper. Individual unit operations and their linkage into an integrated cycle are being developed by a Canadian consortium, as part of the Generation IV International Forum (GIF) for hydrogen production with the next generation of nuclear reactors. This paper focuses on the consortium's latest advances on the Cu-Cl cycle, particularly with respect to hydrogen production with Canada's Generation IV reactor, called SCWR (Super-Critical Water Reactor). Other heat sources may also be utilized for the Cu-Cl cycle, such as solar energy or industrial waste heat. In this first of two companion papers, recent developments in Canada's nuclear hydrogen program are reported, specifically unit operation experiments of the Cu-Cl cycle and system integration. The following second companion paper will present system modeling with Aspen Plus, corrosion resistant materials, thermochemistry, safety, and reliability aspects of the Cu-Cl cycle. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：15472 / 15485

页数：14

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