Solvent Extraction of Ni(II) from Strong Hydrochloric Acid Solution by Alamine336

被引：4
|
作者：
Lee, Man-Seung [2 ]
Nam, Sang-Ho [1 ]
机构：
[1] Mokpo Natl Univ, Dept Chem, Chungnam 534729, South Korea
[2] Mokpo Natl Univ, Dept Adv Mat Sci & Engn, Chungnam 534729, South Korea
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2011年 / 32卷 / 01期
关键词：
Ni(II); HCl; Alamine336; Solvent extraction; CHLORIDE SOLUTIONS; COBALT CHLORIDE; SODIUM-SALTS; SEPARATION; EQUILIBRIA; NICKEL(II); D2EHPA; NI;
D O I：
10.5012/bkcs.2011.32.1.113
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Slope analysis method was applied to determine the stoichiometry of the solvent extraction reaction of Ni(II) by Alamine336 from strong HCl solution range from 1 to 10 M. Solvent extraction data was obtained from the literature. The effective equilibrium constant for the solvent extraction reaction was estimated by considering the ionic equilibria of NiCl2 in the HCl solution. The measured distribution coefficients of Ni(II) agreed well with those calculated in this study. Our results suggest that further study on the measurement of the activities of nickel complexes at high HCl solution need to be done.
引用
收藏
页码：113 / 116
页数：4
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