Stimulated and dynamic nuclear polarisation in photochemical radical reactions

被引：0
|
作者：
Bagryanskaya, EG [1 ]
Sagdeev, RZ [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Int Tomog Ctr, Novosibirsk 630090, Russia
来源：
USPEKHI KHIMII | 2000年 / 69卷 / 11期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly sensitive time-resolved magnetic resonance techniques, based on the influence of radio-frequency and switching magnetic fields on the nuclear polarization diamagnetic radical products are considered. The applications of these methods to the investigation of short-lived radical intermediates (radical pairs, biradicals, free radicals and radical-ions) formed in photochemical reactions in homogeneous and molecular-organised media are discussed.
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页码：1009 / 1031
页数：23
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