Palladium-catalyzed denitrative Sonogashira-type cross-coupling of nitrobenzenes with terminal alkynes

被引：37
|
作者：
Feng, Boya [1 ]
Yang, Yudong [1 ]
You, Jingsong [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, 29 Wangjiang Rd, Chengdu 610064, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 05期
关键词：
BOND ACTIVATION; ARYL; ALKYNYLATION; COPPER; SALTS; HETEROCYCLES; CYCLIZATION; CHLORIDES; CLEAVAGE; ETHERS;
D O I：
10.1039/c9cc08663c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Described herein is a palladium-catalyzed cross-coupling reaction between nitroarenes and terminal alkynes, offering a facile method for C(sp(2))-C(sp) bond formation. The utility of this protocol has been proven by the construction of polycyclic aromatic hydrocarbons (PAHs) and orthogonal cross-coupling.
引用
收藏
页码：790 / 793
页数：4
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