Rhodium-Catalyzed Asymmetric [2+2+2] Cyclization of 1,6-Enynes and Aldehydes

被引：30
|
作者：
Ishida, Mana [1 ]
Shibata, Yu [1 ]
Noguchi, Keiichi [2 ]
Tanaka, Ken [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Dept Appl Chem, Grad Sch Engn, Koganei, Tokyo 1848588, Japan
[2] Tokyo Univ Agr & Technol, Instrumentat Anal Ctr, Koganei, Tokyo 1848588, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 45期
关键词：
aldehydes; asymmetric catalysis; cyclization; enynes; rhodium; CARBOCYCLIZATION REACTIONS; UNSATURATED-HYDROCARBONS; ACYL PHOSPHONATES; CYCLOADDITION; CONSTRUCTION; 1,6-DIYNES; INSERTION; KETONES; DIYNES; ENYNES;
D O I：
10.1002/chem.201102418
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Asymmetric catalysis: The rhodium-catalyzed asymmetric [2+2+2] cyclization of 1,6-enynes and aldehydes was achieved by using a cationic rhodium(I)/(R)-binap complex as a catalyst (see scheme; cod=1,5-cyclooctadiene). Coordination of the substrate heteroatom to the cationic rhodium plays an important role in this cyclization reaction. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12578 / 12581
页数：4
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