Adaptation of bulk constitutive equations to insoluble monolayer collapse at the air-water interface

被引：33
|
作者：
Kampf, JP
Frank, CW [1 ]
Malmström, EE
Hawker, CJ
机构：
[1] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA
[2] IBM Corp, Almaden Res Ctr, San Jose, CA 95120 USA
来源：
SCIENCE | 1999年 / 283卷 / 5408期
关键词：
D O I：
10.1126/science.283.5408.1730
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
A constitutive equation based on stress-strain models of bulk solids was adapted to relate the surface pressure, compression rate, and temperature of an insoluble monolayer of monodendrons during collapse at the air-water interface. power Law relation between compression rate and surface pressure and an Arrhenius temperature dependence of the steady-state creep rate were observed in data from compression rate and creep experiments in the collapse region. These relations were combined into a single constitutive equation to calculate the temperature dependence of the collapse pressure with a maximum error of 5 percent for temperatures ranging from 10 degrees to 25 degrees C.
引用
收藏
页码：1730 / 1733
页数：4
相关论文
共 50 条
  • [1] Adaptation of bulk constitutive equations to insoluble monolayer collapse at the air-water interface
    Kampf, J. Patrick
    Frank, Curtis W.
    Malmstrom, Eva E.
    Hawker, Craig J.
    Science, 283 (5408): : 1730 - 1733
  • [2] INSOLUBLE MONOLAYER OF [C-14] CHLORAMPHENICOL PALMITATE AT AIR-WATER INTERFACE
    IWAHASHI, M
    ARUGA, K
    HIRATA, O
    HORIUCHI, T
    MURAMATS.M
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1973, 42 (02) : 349 - 357
  • [3] Novel pattern formation in the collapse process of floating monolayer at the air-water interface
    E. Hatta
    H. Hosoi
    H. Akiyama
    T. Ishii
    K. Mukasa
    The European Physical Journal B - Condensed Matter and Complex Systems, 1998, 2 : 347 - 349
  • [4] Novel pattern formation in the collapse process of floating monolayer at the air-water interface
    Hatta, E
    Hosoi, H
    Akiyama, H
    Ishii, T
    Mukasa, K
    EUROPEAN PHYSICAL JOURNAL B, 1998, 2 (03): : 347 - 349
  • [5] Dynamic Mechanical Properties of a Polyelectrolyte Adsorbed Insoluble Lipid Monolayer at the Air-Water Interface
    Park, Chang Young
    Kim, Mahn Won
    JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (16): : 5315 - 5320
  • [6] Photoisomerization of the monolayer films on the air-water interface
    Koo, CG
    Song, KH
    Park, TG
    Park, KH
    Kwon, YS
    PROCEEDINGS OF THE 5TH INTERNATIONAL CONFERENCE ON PROPERTIES AND APPLICATIONS OF DIELECTRIC MATERIALS, VOLS 1 AND 2, 1997, : 335 - 337
  • [7] Hydrodynamics of monolayer domains at the air-water interface
    Lubensky, DK
    Goldstein, RE
    PHYSICS OF FLUIDS, 1996, 8 (04) : 843 - 854
  • [8] Study on octadecylamine monolayer at the air-water interface
    Fang, K
    Zou, G
    He, PS
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2002, 15 (04): : 312 - 316
  • [9] SURFACE POTENTIALS OF INSOLUBLE MONOLAYERS AT AIR-WATER INTERFACE
    DEMCHAK, RJ
    FORT, T
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1972, 164 (AUG-S): : 14 - &
  • [10] Kinetics for the collapse of trilayer liquid-crystalline disks from a monolayer at an air-water interface
    Rugonyi, S
    Smith, EC
    Hall, SB
    LANGMUIR, 2005, 21 (16) : 7303 - 7307
12345