Equilibrium Phase Behavior of the Square-Well Linear Microphase-Forming Model

被引:42
|
作者
Zhuang, Yuan [1 ]
Charbonneau, Patrick [1 ,2 ]
机构
[1] Duke Univ, Dept Chem, Durham, NC 27708 USA
[2] Duke Univ, Dept Phys, Durham, NC 27708 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2016年 / 120卷 / 26期
基金
美国国家科学基金会;
关键词
BLOCK-COPOLYMER LITHOGRAPHY; MONTE-CARLO ALGORITHM; PROTEIN SOLUTIONS; CLUSTERS; SYSTEMS; THERMODYNAMICS; TRANSITIONS; SEPARATION; PATTERNS; COLLOIDS;
D O I
10.1021/acs.jpcb.6b02167
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have recently developed a simulation approach to calculate the equilibrium phase diagram of particle-based microphase formers. Here, this approach is used to calculate the phase behavior of the square-well linear model for different strengths and ranges of the linear long-range repulsive component. The results are compared with various theoretical predictions for microphase formation. The analysis further allows us to better understand the mechanism for microphase formation in colloidal suspensions.
引用
收藏
页码:6178 / 6188
页数:11
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