Angelica Lactones: From Biomass-Derived Platform Chemicals to Value-Added Products

被引:78
|
作者
Lima, Carolina G. S. [1 ]
Monteiro, Julia L. [1 ]
Lima, Thiago de Melo [1 ]
Paixao, Marcio Weber [1 ]
Correa, Arlene G. [1 ]
机构
[1] Fed Univ Sao Carlos UFSCar, Dept Chem, Ctr Excellence Res Sustainable Chem CERSusChem, Via Washington Luis,Km 235-SP-310, BR-13565905 Sao Carlos, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
angelica lactones; biomass; levulinic acid; Michael addition; nucleophiles; GAMMA-SUBSTITUTED BUTENOLIDES; VINYLOGOUS MICHAEL REACTIONS; LEVULINIC ACID; DECONJUGATED BUTENOLIDES; ENANTIOSELECTIVE SYNTHESIS; HETEROGENEOUS CATALYSTS; ROOM-TEMPERATURE; MILD CONDITIONS; VALEROLACTONE; CONVERSION;
D O I
10.1002/cssc.201701469
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The upgrading of biomass-derived compounds has arisen in recent years as a very promising research field in both academia and industry. In this sense, a lot of new processes and products have been developed, often involving levulinic acid as a starting material or intermediate. In the last few years, though, other scaffolds have been receiving growing attention, especially, angelica lactones. Considering these facts and the emergent applications of said molecules, in this review we will discuss their preparation and applications; the use of these frameworks as starting materials in organic synthesis to produce potential bioactive compounds will be covered, as will their use as a foundation to highly regarded compounds such as liquid alkanes with prospective use as fuels and polymers.
引用
收藏
页码:25 / 47
页数:23
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