Prediction of vibrational energy levels for the CO molecule and 7Li2 dimer

被引:1
|
作者
Liu, Jun-Zhe [1 ]
Jia, Chun-Sheng [2 ]
机构
[1] Sichuan Univ, Coll Math, Chengdu 610065, Peoples R China
[2] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Peoples R China
基金
中国国家自然科学基金;
关键词
Schrodinger equation; Improved Poschl-Teller potential; Energy spectrum; Carbon monoxide; Lithium dimer; GIBBS FREE-ENERGY; A(3)SIGMA(+)(U) STATE; EQUATION;
D O I
10.1016/j.cplett.2022.139791
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Through solving the Schrodinger equation with the improved Poschl-Teller potential energy model, we obtain a new vibration???rotation energy spectrum representation for diatomic molecules. Using the developed energy spectrum expression and experimental data of four molecular constants for the X-1 Sigma(+) state of the CO molecule and the a(3)Sigma(+)(u) state of Li-7(2) dimer, we predict the vibrational energy levels. The predicted values from the improved Poschl-Teller potential are in better agreement with the vibrational energy values of the direct potential fit and experimentally observed data reported in the literature than those obtained from the improved Tietz potential.
引用
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页数:6
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