R&D of the palladium alloy used for the hydrogen osmosis

被引:0
|
作者
Zeng, LY [1 ]
Yuan, HM [1 ]
Li, SJ [1 ]
机构
[1] NW Inst Nonferrous Met Res, Xian 710016, Peoples R China
关键词
palladium alloy; permeability; order-disorder transition;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The influence of the alloying elements and microstructures on the hydrogen permeability of a Pd alloy are reviewed. The hydrogen permeabilities of the alloys Pd-RE (the alloy Pd-Y especially) are superior to that of the alloy Pd - 25at%Ag which is presently wide use. A major factor affecting the hydrogen permeability is an order-disorder transition. The influence of the order-disorder transition on the hydrogen permeabilities of the alloys Pd-Ce and Pd-Gd has been extensively studied, although their hydrogen permeabilities are not good as the alloy Pd-Y. From the curve of electrical resistance vs. temperature, it can be concluded that a Pd3Y short-range-order superlattice and a Pd7Y long-range-order (LRO) superlattice exist in the alloy Pd-Y. It is thought that the Pd7Y LRO superlattice is transformed from the Pd3Y.
引用
收藏
页码:194 / 198
页数:5
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