Deoxydehydration with Molecular Hydrogen over Ceria-Supported Rhenium Catalyst with Gold Promoter

被引：108
|
作者：
Tazawa, Shuhei [1 ]
Ota, Nobuhiko [1 ]
Tamura, Masazumi [1 ,3 ]
Nakagawa, Yoshinao [1 ,3 ]
Okumura, Kazu [2 ]
Tomishige, Keiichi [1 ,3 ]
机构：
[1] Tohoku Univ, Grad Sch Engn, Dept Appl Chem, Aoba Ku, Aoba 6-6-07, Sendai, Miyagi 9808579, Japan
[2] Kogakuin Univ, Dept Appl Chem, Fac Engn, Nakano Machi 2665-1, Hachioji, Tokyo 1920015, Japan
[3] Tohoku Univ, Res Ctr Rare Met & Green Innovat, Aoba Ku, Aoba 468-1, Sendai, Miyagi 9808579, Japan
来源：
ACS CATALYSIS | 2016年 / 6卷 / 10期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
heterogeneous catalysis; rhenium oxide; gold; deoxydehydration; glycerol; ERYTHRITOL PRODUCTION; CANDIDA-MAGNOLIAE; BIOMASS; CHEMICALS; POLYOLS; GLYCOLS; DIOLS; GLYCEROL; HYDRODEOXYGENATION; DEOXYGENATION;
D O I：
10.1021/acscatal.6b01864
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Gold nanoparticle cocatalyst and ceria support catalyst enabled the use of H-2 as a reductant for Re-catalyzed deoxydehydration (DODH), converting vicinal diols to olefins with higher activity than homogeneous Re catalysts using non-H-2 reductants and with comparable selectivity. The suitable particle size (similar to 10 nm) of Au in ReOx-Au/CeO2 catalyst was especially effective for activating H-2 while retaining the C=C bond in DODH products. Glycerol was converted to ally! alcohol in 91% yield, and the TON per Re atom reached 300. This system is applicable to other substrates such as erythritol (81% yield of 1,3-butadiene).
引用
收藏
页码：6393 / 6397
页数：5
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