Allylic phosphinates via palladium-catalyzed allylation of H-phosphinic acids with allylic alcohols

被引：42
|
作者：
Coudray, Laetitia [1 ]
Bravo-Altamirano, Karla [1 ]
Montchamp, Jean-Luc [1 ]
机构：
[1] Texas Christian Univ, Dept Chem, Ft Worth, TX 76129 USA
来源：
ORGANIC LETTERS | 2008年 / 10卷 / 06期
关键词：
D O I：
10.1021/ol8000415
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel catalytic allylation of H-phosphinic acids is described. Using Pd/xantphos (2 mol %), H-phosphinic acids react directly with allylic alcohols to produce P-allylated disubstituted phosphinic acids.
引用
收藏
页码：1123 / 1126
页数：4
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